Spontaneous Emission | previous | next | feedback |
Definition: a quantum effect, causing the spontaneous decay of excited states of atoms or ions
When an atom (or a laser ion in a gain medium) is excited into a higher-lying energy level, e.g. by absorption of a photon, it may after some time spontaneously return to its ground state, or to some intermediate energy level, by releasing the energy in the form of a photon, which carries the energy in some random direction. (More precisely, the photon can correspond to any propagation mode of the medium surrounding the atom or ion.) This process is called spontaneous emission.
Spontaneous emission is a quantum effect, which in a semiclassical picture can be described as an emission which is stimulated by vacuum noise, i.e., by the vacuum fluctuations of the optical field. This view is supported by the fact that spontaneous emission can be suppressed or modified by placing an atom or ion in a microcavity structure, which modifies the mode structure of the optical field. This shows that spontaneous emission results from an interaction with an excited atom with the optical field, rather than being performed just by the emitting atom itself.
The rate of spontaneous emission (and thus the lifetime of the excited level) is determined both by properties of the atom and by the mode structure of the surrounding medium. For an atom in free space (or in a homogeneous medium), cross sections can be used for calculating the rate of spontaneous emission events (→ radiative lifetime). Typical upper-state lifetimes of atoms are a few nanoseconds if there are allowed transitions to lower levels; much longer values can occur for forbidden transitions.
Light produced by spontaneous emission is called fluorescence. The fluorescence emitted by a laser gain medium typically carries a total power which equals around one tenths to one third of the laser's output power. The spectrum of the emitted fluorescence is essentially governed by transition cross sections.
Bibliography
| [1] | D. Kleppner, "Inhibited spontaneous emission", Phys. Rev. Lett. 47 (4), 233 (1981) |
| [2] | J. J. Sanchez-Mondragon and N. B. Narozhny, "Theory of spontaneous-emission line shape in an ideal cavity", Phys. Rev. Lett. 51 (7), 550 (1983) |
| [3] | S. Noda et al., "Spontaneous emission control by photonic crystals and nanocavities", Nat. Photonics 1, 449 (2007) |
See also: stimulated emission, quantum noise, upper state lifetime, cross sections, fluorescence, laser threshold, parametric fluorescence
Categories: fluctuations and noise, quantum optics
