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Inhomogeneous Broadening

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Definition: the increase in the linewidth of an atomic transition caused by effects which act differently on different radiating or absorbing atoms

German: inhomogene Verbreiterung

Category: physical foundations

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Inhomogeneous broadening is an increase in the linewidth of an atomic transition caused by effects which cause different radiating or absorbing atoms (or ions) to interact with different wavelength components. (Examples for such effects are discussed below.) This means that the absorption and emission cross sections have different spectral shapes for different atoms. The fluorescence spectrum from such a material can then exhibit peaks which are broader than those of single atoms, since it shows an average over many differently emitting atoms. In similar ways, absorption spectra can be broadened.

Inhomogeneous broadening can be caused in various ways:

Inhomogeneous broadening is strongly related to inhomogeneous saturation in laser gain media.

See also: linewidth, inhomogeneous saturation, homogeneous broadening, gain media, gain bandwidth
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