Inhomogeneous broadening is an increase in the linewidth of an atomic transition caused by effects which cause different radiating or absorbing atoms (or ions) to interact with different wavelength components. (Examples for such effects are discussed below.) This means that the absorption and emission cross sections have different spectral shapes for different atoms. The fluorescence spectrum from such a material can then exhibit peaks which are broader than those of single atoms, since it shows an average over many differently emitting atoms. In similar ways, absorption spectra can be broadened.
Inhomogeneous broadening can be caused in various ways:
- Different velocities of the atoms of a gas (e.g. in a gas laser) cause different Doppler shifts.
- In a solid medium, there can be different lattice locations e.g. of laser-active ions, where the ions experience different local electric and magnetic fields. This is particularly the case for glasses, but can also occur in crystalline materials (particularly in disordered crystals).