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Optical Frequency Standards

Definition: frequency standards using optical transitions in atoms, ions or molecules

More general terms: frequency metrology instruments, optical metrology instruments

German: optische Frequenzstandards

Category: optical metrologyoptical metrology


Cite the article using its DOI: https://doi.org/10.61835/k08

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Frequency standards are devices for producing or probing frequencies. Among all physical quantities, the frequency (or time) is the one which can be measured with by far the highest precision. Optical frequency standards refer to optical frequencies, and are required e.g. for optical clocks, but also for optical fiber communications. Essentially always, the provide laser light from carefully frequency-stabilized lasers, or are used to stabilize the frequency of that laser light.

Active and Passive Frequency Standards

An active optical frequency standard is a kind of laser source emitting light with a very well-defined and known optical frequency, or sometimes a set of a few or even many well-defined optical frequency components in a frequency comb. Combined with an optical clockwork, such a frequency standard can form the basis of an optical clock. There are other application areas of ultraprecise optical frequency standards, both in fundamental science and in practical technology, e.g. high-precision laser spectroscopy, global positioning systems, tests of the theory of relativity, and gravitational wave detection.

A passive optical frequency standard is a passive device with a well-defined frequency response, which can be used to build an active standard. Important examples are high-Q reference cavities and devices such as multipass gas cells for probing certain optical transitions.

Standards Based on Optical Transitions

An optical frequency standard is usually based on some optically probed electronic transition (generally a forbidden transition) with narrow bandwidth of certain atoms (e.g. Ca, Rb, Sr, Yb, Mg, or H), ions (Hg^+, Sr^+, Yb^+, In^+, Al^+), or molecules (I2 = iodine, CH4 = methane, C2H2 = acetylene). This transition, which should have a very small bandwidth, is used to stabilize the frequency of a single-frequency laser to the transition frequency. In order to reduce inhomogeneous broadening by thermal movement (Doppler broadening) and collisions, the particles' density and relative velocities have to be minimized. One possibility is to keep the particles in a trap (e.g. a Penning trap or an optical trap) within a vacuum chamber and to apply laser cooling in order to reduce the temperature strongly. This allows for very precise spectroscopic measurements on the clock transition. Alternatively, such measurements can be done on laser-cooled atom beams. Simple gas cells, probed e.g. with Doppler-Free laser absorption spectroscopy, are used when a lower precision is sufficient.

In the future, it may even become possible to use certain low-energy nuclear transitions, for example of 229Th (thorium 229) ions, in order to obtain still higher timing accuracies [14].

To serve well in a high-precision optical atomic clock, an atom, ion or molecule should meet a number of requirements:

  • The clock transition should have a very narrow linewidth (high Q factor).
  • The optical clock frequency should be convenient, so that a suitable interrogation laser is available and further processing (for example the connection to an optical clockwork) is convenient.
  • There should be other transitions suitable for laser cooling.
  • The clock transition should be very insensitive to external disturbing factors such as electric or magnetic fields.

In the case of ions, it is often advantageous to use only a single ion in order to remove disturbances from ion–ion interactions and let the ion sit exactly at the center of the trap. Laser cooling in a trap down to the quantum-mechanical ground state of the ion's motion is then often possible. Interrogation of the clock transition is possible while the trap potential is turned on. Single-ion frequency standards are nearly free from systematic frequency shifts. However, the signal-to-noise ratio for the interrogation is fairly small with a single particle. This is detrimental for the stability of the frequency standard because short-term deviations of the oscillator can not be well suppressed.

Neutral atoms can be used in much larger numbers, such as a million, to improve greatly the signal-to-noise ratio, thus allowing for very high stability of the frequency standard. However, collisions between the atoms lead to uncontrollable frequency shifts. Also, the magneto-optical trap often has to be switched off while interrogating the clock transition because the light field of the trap introduces systematic frequency shifts which are difficult to eliminate. Switching off the trap limits the interaction time and introduces Doppler-related frequency shifts. These problems can be solved by loading the atoms into an optical lattice [8, 12], as can be generated with superimposed laser beams, and by operating the trap with an optical frequency which is adjusted such that it its effects on the upper and lower energy level exactly cancel [12]. Such an optical lattice clock allows the systematic frequency shifts to be largely eliminated.

Reference Cavities as Flywheel Oscillators

As the signal-to-noise ratio for the interrogation of a weak clock transition is typically small (particularly for ion traps), it is important to use a well-stabilized laser as a flywheel oscillator. The laser is typically stabilized to a stable reference cavity with high Q factor, which gives good short-term stability (and can itself be considered as a frequency standard). The clock transition is then used to provide the long-term stability, which the cavity can not guarantee due to various kinds of drifts.

Accuracy, Precision, Stability

The terms accuracy, precision and stability are well distinguished in frequency metrology (and other areas of metrology):

  • A high accuracy means that the produced optical frequency, as measured by averaging over long times, accurately matches the specified frequency.
  • A high precision means that repeated frequency measurements result in values which have a small standard deviation, i.e. which stay close to their mean value.
  • A high stability means that the produced frequency exhibits only weak drifts.

As an example, single-ion frequency standards can be very accurate and stable, but are generally inferior to standards based on atomic clouds in terms of precision.

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